Quantum Computing for Atomic and Molecular Resonances

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Vydáno v:arXiv.org (May 6, 2021), p. n/a
Hlavní autor: Bian, Teng
Další autoři: Kais, Sabre
Vydáno:
Cornell University Library, arXiv.org
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022 |a 2331-8422 
024 7 |a 10.1063/5.0040477  |2 doi 
035 |a 2465898115 
045 0 |b d20210506 
100 1 |a Bian, Teng 
245 1 |a Quantum Computing for Atomic and Molecular Resonances 
260 |b Cornell University Library, arXiv.org  |c May 6, 2021 
513 |a Working Paper 
520 3 |a The complex-scaling method can be used to calculate molecular resonances within the Born-Oppenheimer approximation, assuming the electronic coordinates are dilated independently of the nuclear coordinates. With this method, one will calculate the complex energy of a non-Hermitian Hamiltonian, whose real part is associated with the resonance position and the imaginary part is the inverse of the lifetime. In this study, we propose techniques to simulate resonances on a quantum computer. First, we transformed the scaled molecular Hamiltonian to second-quantization and then used the Jordan-Wigner transformation to transform the scaled Hamiltonian to the qubit space. To obtain the complex eigenvalues, we introduce the Direct Measurement method, which is applied to obtain the resonances of a simple one-dimensional model potential that exhibits pre-dissociating resonances analogous to those found in diatomic molecules. Finally, we applied the method to simulate the resonances of the H\(_2^-\) molecule. Numerical results from the IBM Qiskit simulators and IBM quantum computers verify our techniques. 
653 |a Eigenvalues 
653 |a Measurement methods 
653 |a Diatomic molecules 
653 |a Quantum computing 
653 |a Mathematical analysis 
653 |a One dimensional models 
653 |a Quantum computers 
653 |a Simulation 
653 |a Flight simulators 
653 |a Born-Oppenheimer approximation 
653 |a Qubits (quantum computing) 
700 1 |a Kais, Sabre 
773 0 |t arXiv.org  |g (May 6, 2021), p. n/a 
786 0 |d ProQuest  |t Engineering Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/2465898115/abstract/embedded/6A8EOT78XXH2IG52?source=fedsrch 
856 4 0 |3 Full text outside of ProQuest  |u http://arxiv.org/abs/2011.13999