Pt/Ru-Modified ZnO Sensor Grown In Situ for Detection of ppb H2S

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Publicado en:Sensors vol. 25, no. 7 (2025), p. 1995
Autor Principal: Zhang, Jianhua
Outros autores: Shi, Yunbo, Tang, Bolun, Zheng, Canda
Publicado:
MDPI AG
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100 1 |a Zhang, Jianhua 
245 1 |a Pt/Ru-Modified ZnO Sensor Grown In Situ for Detection of ppb H<sub>2</sub>S 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a This paper presents a ZnO-Pt/Ru sensor prepared by a two-step hydrothermal method with in situ-grown ZnO nanorods and doped with Pt and Ru elements by immersion sintering. Characterization results showed that Pt and Ru were successfully modified on the surface of ZnO nanorods. ZnO-Pt/Ru achieved a response of 25–50 ppm H2S at the optimum operating temperature of 198 °C. In addition, the lower limit of H2S detection of ZnO-Pt/Ru reached 50 ppb with a response of about 10%, indicating a wide concentration detection range. Due to the good catalytic properties of Pt, the recovery characteristics of ZnO at high concentrations of H2S were significantly improved. The response time of ZnO-Pt/Ru (30 s) was also significantly shorter than pristine ZnO (56 s), with excellent selectivity. As far as the gas-sensitive enhancement mechanism is concerned, at the macroscopic level, the ZnO surface was modified by Pt and Ru, and this special structure of ZnO-Pt/Ru significantly increased the specific surface area. At the microscopic level, the PN junction formed between Pt/Ru and ZnO provided abundant holes for electron migration. 
610 4 |a JEOL Ltd 
651 4 |a United States--US 
651 4 |a Shanghai China 
651 4 |a China 
651 4 |a Japan 
653 |a Metals 
653 |a Transmission electron microscopy 
653 |a Nanowires 
653 |a Gases 
653 |a Spectrum analysis 
653 |a Glass substrates 
653 |a Nanoparticles 
653 |a Computer terminals 
653 |a Alumina 
653 |a Sensors 
653 |a Methods 
653 |a Chromatography 
653 |a Morphology 
653 |a Radiation 
653 |a Scanning electron microscopy 
653 |a Composite materials 
653 |a Ethanol 
700 1 |a Shi, Yunbo 
700 1 |a Tang, Bolun 
700 1 |a Zheng, Canda 
773 0 |t Sensors  |g vol. 25, no. 7 (2025), p. 1995 
786 0 |d ProQuest  |t Health & Medical Collection 
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