An Extensive Study of the Production of Hydrogen by Cellulose and Lignin Pyrolysis Using Rhenium-Based Catalysts

שמור ב:
מידע ביבליוגרפי
הוצא לאור ב:Chemistry vol. 7, no. 2 (2025), p. 33
מחבר ראשי: Granados-Fitch, Mizraim Guillermo
מחברים אחרים: Quintana-Melgoza, Juan Manuel, Juarez-Arellano, Erick Adrian, Avalos-Borja, Miguel
יצא לאור:
MDPI AG
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גישה מקוונת:Citation/Abstract
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022 |a 2624-8549 
024 7 |a 10.3390/chemistry7020033  |2 doi 
035 |a 3194533465 
045 2 |b d20250101  |b d20251231 
100 1 |a Granados-Fitch, Mizraim Guillermo  |u Instituto Potosino de Investigación Científica y Tecnológica, División de Materiales Avanzados, Camino a la Presa San José, Col. Lomas, Sección 4, San Luis Potosí C.P. 78216, Mexico 
245 1 |a An Extensive Study of the Production of Hydrogen by Cellulose and Lignin Pyrolysis Using Rhenium-Based Catalysts 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a The use of rhenium-based catalysts (Re2C, Re3B, ReB2, and ReS2) obtained by mechanosynthesis in the pyrolysis of cellulose and lignin from 500 to 800 °C using 10 and 20 wt.% of catalysts is reported. The mechanosynthesis of ReS2 has been reported for the first time. The catalytic pyrolysis of cellulose resulted in maximum H2 production at 800 °C and 10 wt.% catalyst, with 44% H2 yield using a Re3B catalyst. In contrast, lignin catalytic pyrolysis also showed maximum production under the same conditions, with an 86.1% H2 yield using the NiO/SiO2 catalyst; however, the catalyst did not drastically enhance H2 production. H2 formation by cellulose pyrolysis is a thermocatalytic process, whereas lignin pyrolysis is an entirely thermic process. A reaction mechanism was proposed to explain the H2 formation by both catalytic cellulose and lignin pyrolysis. 
651 4 |a Mexico 
651 4 |a United States--US 
653 |a Nuclear energy 
653 |a Hydrogen production 
653 |a Lignin 
653 |a Cellulose 
653 |a Temperature 
653 |a Renewable resources 
653 |a Silicon dioxide 
653 |a Microscopy 
653 |a Sulfur 
653 |a Biomass 
653 |a Rhenium 
653 |a Alternative energy sources 
653 |a Reaction mechanisms 
653 |a Energy resources 
653 |a Heat resistance 
653 |a Pyrolysis 
653 |a Energy consumption 
653 |a Coal 
653 |a Canoes & canoeing 
653 |a Natural gas 
653 |a Catalysts 
700 1 |a Quintana-Melgoza, Juan Manuel  |u Facultad de Ciencias Químicas e Ingeniería, Universidad Autónoma de Baja California, Campus Tijuana, Tijuana C.P. 22424, Mexico 
700 1 |a Juarez-Arellano, Erick Adrian  |u Centro de Investigaciones Científicas, Instituto de Química Aplicada, Universidad del Papaloapan, Circuito central # 200, Col. Parque Industrial, Tuxtepec C.P. 68301, Mexico 
700 1 |a Avalos-Borja, Miguel  |u Instituto Potosino de Investigación Científica y Tecnológica, División de Materiales Avanzados, Camino a la Presa San José, Col. Lomas, Sección 4, San Luis Potosí C.P. 78216, Mexico 
773 0 |t Chemistry  |g vol. 7, no. 2 (2025), p. 33 
786 0 |d ProQuest  |t Materials Science Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3194533465/abstract/embedded/6A8EOT78XXH2IG52?source=fedsrch 
856 4 0 |3 Full Text + Graphics  |u https://www.proquest.com/docview/3194533465/fulltextwithgraphics/embedded/6A8EOT78XXH2IG52?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3194533465/fulltextPDF/embedded/6A8EOT78XXH2IG52?source=fedsrch