Configurable kinetics of polarization switching via ion migration in ferroionic CuInP2S6

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Publicado en:Nature Communications vol. 16, no. 1 (2025), p. 4462
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022 |a 2041-1723 
024 7 |a 10.1038/s41467-025-59697-z  |2 doi 
035 |a 3204145138 
045 2 |b d20250101  |b d20251231 
084 |a 145839  |2 nlm 
245 1 |a Configurable kinetics of polarization switching via ion migration in ferroionic CuInP<sub>2</sub>S<sub>6</sub> 
260 |b Nature Publishing Group  |c 2025 
513 |a Journal Article 
520 3 |a Ferroelectric materials are promising for developing non-volatile memory, neuromorphic computing, and photovoltaic technologies. Taking advantage of variable switching kinetics provides an important strategy for designing multifunctional ferroelectric devices. However, the conventional ferroelectrics due to the unmovable atomic species generally own a single switching kinetics, thus versatile and configurable switching kinetics still remain challenging. In this work, we systematically investigate the switching kinetics of the van der Waals ferroionic CuInP2S6 through polarization-determined ferroelectric photovoltaic behaviors. Based on the time- and field-dependent polarization switching and numerical simulation, we discover three switching modes, including intralayer switching, interlayer switching and intralayer-interlayer coupling switching in CuInP2S6. Through designing the poling voltage amplitude and width, we achieve the configurable kinetic control of polarization switching in CuInP2S6, enabling tunable binary, gradual and accumulative switching with defined poling voltages in a single device. The work demonstrated here is instructive for the development of nanoscale multifunctional ferroelectric devices.The authors achieve configurable ferroelectric switching kinetics in CuInP2S6 through precisely tuning the Cu ions interlayer hopping, paving the way for development of advanced multifunctional ferroelectric devices. 
653 |a Kinetics 
653 |a Polarization 
653 |a Photovoltaics 
653 |a Ferroelectricity 
653 |a Interlayers 
653 |a Ion migration 
653 |a Mathematical models 
653 |a Ferroelectric materials 
653 |a Environmental 
773 0 |t Nature Communications  |g vol. 16, no. 1 (2025), p. 4462 
786 0 |d ProQuest  |t Health & Medical Collection 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3204145138/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3204145138/fulltextPDF/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch