Inference of Indium Competition on the Optical Characteristics of GaAs/InxGa1−xAs Core–Shell Nanowires with Reverse Type-I Band Alignment

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Publicat a:Materials vol. 18, no. 17 (2025), p. 4030-4042
Autor principal: Wang Puning
Altres autors: Liu, Huan, Kang Yubin, Tang Jilong, Hao Qun, Wei Zhipeng
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MDPI AG
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022 |a 1996-1944 
024 7 |a 10.3390/ma18174030  |2 doi 
035 |a 3249703462 
045 2 |b d20250101  |b d20251231 
084 |a 231532  |2 nlm 
100 1 |a Wang Puning  |u State Key Laboratory of High-Power Semiconductor Laser, School of Physics, Changchun University of Science and Technology, Changchun 130022, China; puning_wang@163.com (P.W.); yubinkangcust@126.com (Y.K.); jl_tangcust@163.com (J.T.); qhao@bit.edu.cn (Q.H.) 
245 1 |a Inference of Indium Competition on the Optical Characteristics of GaAs/In<i><sub>x</sub></i>Ga<sub>1−<i>x</i></sub>As Core–Shell Nanowires with Reverse Type-I Band Alignment 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a One-dimensional GaAs/InGaAs core–shell nanowires (NWs) with reverse type-I band alignment are promising candidates for next-generation optoelectronic devices. However, the influence of composition gradients and atomic interdiffusion at the core–shell interface on their photoluminescence (PL) behavior remains to be clarified. In this work, GaAs/InxGa1−xAs NW arrays with different indium (In) compositions were prepared using molecular beam epitaxy (MBE), and their band alignment and optical responses were systematically investigated through power and temperature-dependent PL spectra. The experiments reveal that variations in the In concentration gradient modify the characteristics of potential wells within the composition graded layer (CGL), as reflected by distinct PL emission features and thermal activation energies. At elevated temperatures, carrier escape from these wells is closely related to the observed PL saturation and emission quenching. These results provide experimental insight into the relationship between composition gradients, carrier dynamics, and emission properties in GaAs/InGaAs core–shell NWs, making them promising candidates for high-performance nanoscale optoelectronic device design. 
653 |a Transmission electron microscopy 
653 |a Organic chemicals 
653 |a Alignment 
653 |a Nanowires 
653 |a Temperature dependence 
653 |a Fourier transforms 
653 |a Interdiffusion 
653 |a Emission 
653 |a Concentration gradient 
653 |a Molecular beam epitaxy 
653 |a Indium gallium arsenides 
653 |a Indium 
653 |a Gallium arsenide 
653 |a Optoelectronic devices 
653 |a Composition 
653 |a High temperature 
653 |a Morphology 
653 |a Scanning electron microscopy 
653 |a Photoluminescence 
653 |a Optical properties 
700 1 |a Liu, Huan  |u Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China; 12149014@mail.sustech.edu.cn 
700 1 |a Kang Yubin  |u State Key Laboratory of High-Power Semiconductor Laser, School of Physics, Changchun University of Science and Technology, Changchun 130022, China; puning_wang@163.com (P.W.); yubinkangcust@126.com (Y.K.); jl_tangcust@163.com (J.T.); qhao@bit.edu.cn (Q.H.) 
700 1 |a Tang Jilong  |u State Key Laboratory of High-Power Semiconductor Laser, School of Physics, Changchun University of Science and Technology, Changchun 130022, China; puning_wang@163.com (P.W.); yubinkangcust@126.com (Y.K.); jl_tangcust@163.com (J.T.); qhao@bit.edu.cn (Q.H.) 
700 1 |a Hao Qun  |u State Key Laboratory of High-Power Semiconductor Laser, School of Physics, Changchun University of Science and Technology, Changchun 130022, China; puning_wang@163.com (P.W.); yubinkangcust@126.com (Y.K.); jl_tangcust@163.com (J.T.); qhao@bit.edu.cn (Q.H.) 
700 1 |a Wei Zhipeng  |u State Key Laboratory of High-Power Semiconductor Laser, School of Physics, Changchun University of Science and Technology, Changchun 130022, China; puning_wang@163.com (P.W.); yubinkangcust@126.com (Y.K.); jl_tangcust@163.com (J.T.); qhao@bit.edu.cn (Q.H.) 
773 0 |t Materials  |g vol. 18, no. 17 (2025), p. 4030-4042 
786 0 |d ProQuest  |t Materials Science Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3249703462/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text + Graphics  |u https://www.proquest.com/docview/3249703462/fulltextwithgraphics/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3249703462/fulltextPDF/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch