Effect of Ultrasonic Treatment on Chemical Stripping Behavior of Aluminum Coating on K6509 Co-Based Superalloy

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Publicado en:Materials vol. 18, no. 17 (2025), p. 3979-4000
Autor principal: Jin, Yuanyuan
Otros Autores: Xie, Cheng, Sun, Ke, Li Zehuan, Wang, Xin, Ma, Xin, Wang, Hui, Shang Rongrong, Zhou Xuxian, Li, Yidi, Li, Yunping
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MDPI AG
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022 |a 1996-1944 
024 7 |a 10.3390/ma18173979  |2 doi 
035 |a 3249703481 
045 2 |b d20250101  |b d20251231 
084 |a 231532  |2 nlm 
100 1 |a Jin, Yuanyuan  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
245 1 |a Effect of Ultrasonic Treatment on Chemical Stripping Behavior of Aluminum Coating on K6509 Co-Based Superalloy 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a In this study, 10% nitric acid was employed to remove the aluminum coating on the cobalt-based superalloy K6509, with a focus on elucidating the corrosion mechanism and evaluating the effect of ultrasonic on the removal process. The results shows that ultrasonic treatment (40 kHz) significantly improves coating removal efficiency, increasing the maximum corrosion rate by 46.49% from 2.5413 × 10−7 g·s−1·mm−2 to 4.7488 × 10−7 g·s−1·mm−2 and reducing removal time from 10 min to 6 min. This enhancement is attributed to cavitation effect of ultrasonic bubbles and the shockwave-accelerated ion diffusion, which together facilitate more efficient coating degradation and results in a smoother surface. In terms of corrosion behavior, the difference in phase composition between the outer layer and the interdiffusion zone (IDZ) plays a decisive role. The outer layer is primarily composed of β-(Co,Ni)Al phase, which is thermodynamically less stable in acidic environments and thus readily dissolves in 10% HNO3. In contrast, the IDZ mainly consists of Cr23C6, which exhibit high chemical stability and a strong tendency to passivate. These characteristics render the IDZ highly resistant to nitric acid attack, thereby forming a protective barrier that limits acid penetration and helps maintain the integrity of the substrate. 
651 4 |a Japan 
653 |a Turbines 
653 |a Thermal cycling 
653 |a Acid resistance 
653 |a Corrosion mechanisms 
653 |a Electrodes 
653 |a Substrates 
653 |a Interdiffusion 
653 |a Ultrasonic processing 
653 |a Microscopy 
653 |a Protective coatings 
653 |a Etching 
653 |a Aluminum 
653 |a Phase composition 
653 |a Superalloys 
653 |a Aluminum coatings 
653 |a Corrosion rate 
653 |a Nitric acid 
653 |a Cavitation 
653 |a Remanufacturing 
653 |a Cobalt base alloys 
653 |a Ion diffusion 
653 |a Corrosion 
700 1 |a Xie, Cheng  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
700 1 |a Sun, Ke  |u Aero Engine Corporation of China, South Industry Co., Ltd., Zhuzhou 412002, China 
700 1 |a Li Zehuan  |u Aero Engine Corporation of China, South Industry Co., Ltd., Zhuzhou 412002, China 
700 1 |a Wang, Xin  |u Aero Engine Corporation of China, South Industry Co., Ltd., Zhuzhou 412002, China 
700 1 |a Ma, Xin  |u Aero Engine Corporation of China, South Industry Co., Ltd., Zhuzhou 412002, China 
700 1 |a Wang, Hui  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
700 1 |a Shang Rongrong  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
700 1 |a Zhou Xuxian  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
700 1 |a Li, Yidi  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
700 1 |a Li, Yunping  |u State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; jinyuanyuan83@csu.edu.cn (Y.J.); youxianboy@163.com (C.X.); 
773 0 |t Materials  |g vol. 18, no. 17 (2025), p. 3979-4000 
786 0 |d ProQuest  |t Materials Science Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3249703481/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
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