Growth Behavior of Multi-Element Compound Layers During Reactive Diffusion Between Solid CoCrFeMnNi Alloy and Liquid Al

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Vydáno v:Materials vol. 18, no. 17 (2025), p. 4158-4174
Hlavní autor: Yang Longtu
Další autoři: Yang, Yufeng, Yao Zeqiang, Liu, Shichao, Dong, Yong
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MDPI AG
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022 |a 1996-1944 
024 7 |a 10.3390/ma18174158  |2 doi 
035 |a 3249703740 
045 2 |b d20250101  |b d20251231 
084 |a 231532  |2 nlm 
100 1 |a Yang Longtu  |u Innovation Research Institute of Low Carbon Metallurgical Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China 
245 1 |a Growth Behavior of Multi-Element Compound Layers During Reactive Diffusion Between Solid CoCrFeMnNi Alloy and Liquid Al 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a In the present study, the diffusion couple of solid CoCrFeMnNi HEA and liquid pure Al was prepared. The microstructure evolution and relevant interdiffusion behavior of CoCrFeMnNi HEA/Al solid–liquid diffusion couple processed by different parameters were characterized and investigated. Results demonstrated that the interfacial compounds in the order of Al(Co, Cr, Fe, Mn, Ni), Al13(Co, Cr, Fe, Mn, Ni)4 and Al4(Co, Cr, Fe, Mn, Ni) were determined in the interdiffusion area along the direction from CoCrFeMnNi HEA to Al, and the precipitated Al4(Cr, Mn) and Al9(Co, Fe, Ni) phases were formed in the center of Al couple. In addition, the diffusion mechanism and activation energy of growth for each diffusion layer were revealed and determined. More importantly, the growth mechanism of each diffusion layer was also investigated and uncovered in detail. Meanwhile, the activation energy of each intermetallic layer was obtained by the Arrhenius equation and the linear regression method. It is anticipated that this present study would provide a fundamental understanding and theoretical basis for the high-entropy alloy CoCrFeMnNi HEA, potentially applied as the cast mold material for cast aluminum alloy. 
653 |a Mechanical properties 
653 |a Thermal cycling 
653 |a Iron 
653 |a Interdiffusion 
653 |a Temperature 
653 |a High entropy alloys 
653 |a Nickel 
653 |a Aluminum alloys 
653 |a Cobalt 
653 |a Diffusion layers 
653 |a Intermetallic compounds 
653 |a Activation energy 
653 |a Alloys 
653 |a Manganese 
653 |a Heat resistance 
653 |a Heat conductivity 
653 |a Aluminum base alloys 
653 |a Morphology 
653 |a Entropy 
653 |a Chromium 
653 |a Corrosion 
700 1 |a Yang, Yufeng  |u Innovation Research Institute of Low Carbon Metallurgical Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China 
700 1 |a Yao Zeqiang  |u Innovation Research Institute of Low Carbon Metallurgical Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China 
700 1 |a Liu, Shichao  |u School of Tron and Steel, Soochow University, Suzhou 215021, China; sc_liu@suda.edu.cn 
700 1 |a Dong, Yong  |u Innovation Research Institute of Low Carbon Metallurgical Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China 
773 0 |t Materials  |g vol. 18, no. 17 (2025), p. 4158-4174 
786 0 |d ProQuest  |t Materials Science Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3249703740/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text + Graphics  |u https://www.proquest.com/docview/3249703740/fulltextwithgraphics/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3249703740/fulltextPDF/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch