Microstructure Evolution and Damage Mechanism of DD9 Single Crystal Superalloy-Thermal Barrier Coating System Under High Temperature Oxidation: A Comparative Study with DD6

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Publicado en:Materials vol. 18, no. 18 (2025), p. 4332-4352
Autor principal: Pan, Li
Otros Autores: Xin Zhenyu, Sun, Fan, Jin Xiaochao, Zhang, Chao
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MDPI AG
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024 7 |a 10.3390/ma18184332  |2 doi 
035 |a 3254597838 
045 2 |b d20250101  |b d20251231 
084 |a 231532  |2 nlm 
100 1 |a Pan, Li  |u School of Civil Aviation, Northwestern Polytechnical University, Xi’an 710072, China; lp0816@nwpu.edu.cn 
245 1 |a Microstructure Evolution and Damage Mechanism of DD9 Single Crystal Superalloy-Thermal Barrier Coating System Under High Temperature Oxidation: A Comparative Study with DD6 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a This study investigates the microstructural evolution and damage mechanisms of the nickel-based single-crystal superalloy DD9-thermal barrier coating (TBC) system under 1050 °C high-temperature oxidation, while conducting a comparative analysis of oxidation behavior with the DD6-TBC system. Results show that both systems have similar oxidation mechanisms but face long-term oxidation drawbacks: as oxidation time increases, the thermally grown oxide (TGO) evolves into a mixed oxide layer and an Al2O3 layer, with initial rapid TGO growth consuming Al in the bond coat (BC) and subsequent Al depletion slowing growth, though long-term TGO accumulation raises cracking and spallation risks. DD9 and DD6 substrates significantly affect substrate-BC interfacial interdiffusion: the interdiffusion zone (IDZ) and secondary reaction zone (SRZ) grow continuously (SRZ growing faster), and linear topologically close-packed (TCP) phases precipitate in the SRZ, spreading throughout the substrate and impairing high-temperature mechanical properties. Specifically, DD9’s IDZ growth rate is faster than DD6’s in the first 800 h of oxidation but slows below DD6’s afterward, reflecting DD9’s superior long-term oxidation resistance due to better temperature resistance and high-temperature stability. This study clarifies key high-temperature service disadvantages of the two systems, providing experimental support for coated turbine blade life evaluation and a theoretical basis for optimizing third-generation single-crystal superalloy-TBC systems to enhance high-temperature service stability. 
653 |a Mechanical properties 
653 |a Investigations 
653 |a Oxidation resistance 
653 |a Single crystals 
653 |a Mixed oxides 
653 |a High temperature 
653 |a Airplane engines 
653 |a Protective coatings 
653 |a Cracking (fracturing) 
653 |a Thermal barrier coatings 
653 |a Damage 
653 |a Research & development--R&D 
653 |a Superalloys 
653 |a Corrosion 
653 |a Aircraft 
653 |a Turbines 
653 |a Comparative studies 
653 |a Oxidation 
653 |a Substrates 
653 |a Interdiffusion 
653 |a Thermal barriers 
653 |a Aluminum oxide 
653 |a Turbine blades 
653 |a Spallation 
653 |a Stability 
653 |a Nickel 
653 |a Alloys 
653 |a Microstructure 
700 1 |a Xin Zhenyu  |u Xi’an Key Laboratory of Extreme Environment and Protection Technology, School of Aerospace Engineering, Xi’an Jiaotong University, Xi’an 710049, Chinajinxiaochao@xjtu.edu.cn (X.J.) 
700 1 |a Sun, Fan  |u National Key Laboratory of Energetic Materials, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China; sf2038945624@163.com 
700 1 |a Jin Xiaochao  |u Xi’an Key Laboratory of Extreme Environment and Protection Technology, School of Aerospace Engineering, Xi’an Jiaotong University, Xi’an 710049, Chinajinxiaochao@xjtu.edu.cn (X.J.) 
700 1 |a Zhang, Chao  |u School of Civil Aviation, Northwestern Polytechnical University, Xi’an 710072, China; lp0816@nwpu.edu.cn 
773 0 |t Materials  |g vol. 18, no. 18 (2025), p. 4332-4352 
786 0 |d ProQuest  |t Materials Science Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3254597838/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text + Graphics  |u https://www.proquest.com/docview/3254597838/fulltextwithgraphics/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3254597838/fulltextPDF/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch