Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing

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Publicado en:Micromachines vol. 16, no. 3 (2025), p. 242
Autor principal: Nahid Sultan Al-Mamun
Otros Autores: Du, Yuxin, Song, Jianan, Chu, Rongming, Haque, Aman
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MDPI AG
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024 7 |a 10.3390/mi16030242  |2 doi 
035 |a 3181672178 
045 2 |b d20250101  |b d20251231 
084 |a 231537  |2 nlm 
100 1 |a Nahid Sultan Al-Mamun  |u Department of Mechanical Engineering, Penn State University, University Park, PA 16802, USA; <email>nma5621@psu.edu</email> 
245 1 |a Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing 
260 |b MDPI AG  |c 2025 
513 |a Journal Article 
520 3 |a The reliability of GaN-based devices operating under high temperatures is crucial for their application in extreme environments. To identify the fundamental mechanisms behind high-temperature degradation, we investigated GaN-on-sapphire Schottky barrier diodes (SBDs) under simultaneous heating and electrical biasing. We observed the degradation mechanisms in situ inside a transmission electron microscope (TEM) using a custom-fabricated chip for simultaneous thermal and electrical control. The pristine device exhibited a high density of extended defects, primarily due to lattice mismatch and thermal expansion differences between the GaN and sapphire. TEM and STEM imaging, coupled with energy-dispersive X-ray spectroscopy (EDS), revealed the progressive degradation of the diode with increasing bias and temperature. At higher bias levels (4–5 V) and elevated temperatures (300–455 °C), the interdiffusion and alloying of the Au/Pd Schottky metal stack with GaN, along with defect generation near the interface, resulted in Schottky contact failure and catastrophic device degradation. A geometric phase analysis further identified strain localization and lattice distortions induced by thermal and electrical stresses, which facilitated diffusion pathways for rapid metal atom migration. These findings highlight that defect-mediated electrothermal degradation and interfacial chemical reactions are critical elements in the high-temperature failure physics of GaN Schottky diodes. 
653 |a Silicon 
653 |a Microelectromechanical systems 
653 |a Sapphire 
653 |a Bias 
653 |a Chemical reactions 
653 |a Semiconductors 
653 |a Strain localization 
653 |a Electric contacts 
653 |a Misfit dislocations 
653 |a Extreme environments 
653 |a Intermetallic compounds 
653 |a Degradation 
653 |a Transistors 
653 |a Thermal expansion 
653 |a Defects 
653 |a High temperature 
653 |a Gold 
653 |a Transmission electron microscopy 
653 |a Diodes 
653 |a Interdiffusion 
653 |a Gallium nitrides 
653 |a Temperature 
653 |a Failure 
653 |a Etching 
653 |a Palladium 
653 |a Schottky diodes 
700 1 |a Du, Yuxin  |u Department of Electrical Engineering, Penn State University, University Park, PA 16802, USA; <email>yqd5203@psu.edu</email> (Y.D.); <email>jus824@psu.edu</email> (J.S.) 
700 1 |a Song, Jianan  |u Department of Electrical Engineering, Penn State University, University Park, PA 16802, USA; <email>yqd5203@psu.edu</email> (Y.D.); <email>jus824@psu.edu</email> (J.S.) 
700 1 |a Chu, Rongming  |u Department of Electrical Engineering, Penn State University, University Park, PA 16802, USA; <email>yqd5203@psu.edu</email> (Y.D.); <email>jus824@psu.edu</email> (J.S.) 
700 1 |a Haque, Aman  |u Department of Mechanical Engineering, Penn State University, University Park, PA 16802, USA; <email>nma5621@psu.edu</email> 
773 0 |t Micromachines  |g vol. 16, no. 3 (2025), p. 242 
786 0 |d ProQuest  |t Engineering Database 
856 4 1 |3 Citation/Abstract  |u https://www.proquest.com/docview/3181672178/abstract/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text + Graphics  |u https://www.proquest.com/docview/3181672178/fulltextwithgraphics/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch 
856 4 0 |3 Full Text - PDF  |u https://www.proquest.com/docview/3181672178/fulltextPDF/embedded/7BTGNMKEMPT1V9Z2?source=fedsrch